Search results for "Vibrational bands"
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Stimulated Raman and Cars Spectroscopy of ν1 and 2ν2 (A1) Bands of 12CF4
1994
Two experimental coherent Raman techniques, stimulated Raman and coherent anti-Stokes Raman spectroscopy (CARS), were employed to study the Raman spectrum of CF 4 in the 900 cm −1 region. The stimulated Raman and CARS spectra of the ν 1 band of CF 4 were recorded at high resolution. The analysis of these spectra enabled some spectroscopic constants of this band to be refined and higher order constants to be determined for the first time. The first high-resolution CARS spectrum of the 2ν 2 (A 1 ) harmonic band is also presented. The rotational transitions of this band up to J = 40 were assigned and the first set of spectroscopic constants for this sub-level were determined. These results imp…
High resolution study of the six lowest doubly excited vibrational states of PH2D
2005
Abstract The five lowest doubly excited deformational vibrational bands ν 4 + ν 6 , 2 ν 6 , ν 3 + ν 4 , ν 3 + ν 6 , and 2 ν 3 of PH 2 D have been recorded for the first time using a Bruker 120 HR interferometer with a resolution 0.0033 cm −1 and analysed. Some transitions belonging to a very weak band 2 ν 4 have been also assigned. From the fit 24 and 86, respectively, diagonal and resonance interaction parameters were obtained which reproduce 1089 upper energy levels obtained from more than 4600 assigned transitions with the rms deviation of 0.00059 cm −1 .